Palladium-Catalyzed Enantioselective α-Arylation and α-Vinylation of Oxindoles Facilitated by an Axially Chiral P-Stereogenic Ligand
The enantioselective α-arylation and α-vinylation of oxindoles catalyzed by Pd and a biarylmonophosphine ligand with both axial and phosphorus-based chirogenicity is reported. The resultant quaternary carbon stereocenters are formed in high enantiomeric excess, and the conditions tolerate a range of...
Main Authors: | , , |
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其他作者: | |
格式: | 文件 |
语言: | en_US |
出版: |
American Chemical Society (ACS)
2013
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在线阅读: | http://hdl.handle.net/1721.1/81936 https://orcid.org/0000-0003-3875-4775 |