Stille Cross-Coupling Reactions of Aryl Mesylates and Tosylates Using a Biarylphosphine Based Catalyst System

Stille Cross-Coupling Reactions of Aryl Mesylates and Tosylates Using a Biarylphosphine Based Catalyst System

A catalyst system for the Stille cross-coupling reactions of aryl mesylates and tosylates is reported. Using the combination of Pd(OAc)[subscript 2], XPhos, and CsF in t-BuOH an array of aryl and heteroaryl sulfonates were successfully employed in these reactions. Morever, heteroarylstannanes, such...

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Bibliographic Details
Main Authors: Wu, Xiaoxing, Buchwald, Stephen Leffler, Naber, John R., Fors, Brett P., Gunn, Jonathon T.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: Japan Institute of Heterocyclic Chemistry 2013
Online Access:http://hdl.handle.net/1721.1/81939
https://orcid.org/0000-0003-3875-4775

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http://hdl.handle.net/1721.1/81939
https://orcid.org/0000-0003-3875-4775

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