Stille Cross-Coupling Reactions of Aryl Mesylates and Tosylates Using a Biarylphosphine Based Catalyst System
A catalyst system for the Stille cross-coupling reactions of aryl mesylates and tosylates is reported. Using the combination of Pd(OAc)[subscript 2], XPhos, and CsF in t-BuOH an array of aryl and heteroaryl sulfonates were successfully employed in these reactions. Morever, heteroarylstannanes, such...
Main Authors: | Wu, Xiaoxing, Buchwald, Stephen Leffler, Naber, John R., Fors, Brett P., Gunn, Jonathon T. |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
Japan Institute of Heterocyclic Chemistry
2013
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Online Access: | http://hdl.handle.net/1721.1/81939 https://orcid.org/0000-0003-3875-4775 |
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