Evidence for in Situ Catalyst Modification during the Pd-Catalyzed Conversion of Aryl Triflates to Aryl Fluorides

Evidence for in Situ Catalyst Modification during the Pd-Catalyzed Conversion of Aryl Triflates to Aryl Fluorides

A mechanistic investigation of the Pd-catalyzed conversion of aryl triflates to fluorides is presented. Studies reveal that C–F reductive elimination from a LPd[superscript II](aryl)F complex (L = t-BuBrettPhos or RockPhos) does not occur when the aryl group is electron rich. Evidence is presented t...

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Bibliographic Details
Main Authors: Maimone, Thomas, Kinzel, Tom, Zhang, Yong, Takase, Michael K., Milner, Phillip John, Buchwald, Stephen Leffler
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2013
Online Access:http://hdl.handle.net/1721.1/81966
https://orcid.org/0000-0003-3875-4775

Internet

http://hdl.handle.net/1721.1/81966
https://orcid.org/0000-0003-3875-4775

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