Dynamic Nuclear Polarization with a Water-Soluble Rigid Biradical

A new biradical polarizing agent, bTbtk-py, for dynamic nuclear polarization (DNP) experiments in aqueous media is reported. The synthesis is discussed in light of the requirements of the optimum, theoretical, biradical system. To date, the DNP NMR signal enhancement resulting from bTbtk-py is the l...

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Bibliographic Details
Main Authors: Kiesewetter, Matthew K., Smith, Albert A., Corzilius, Bjorn, Griffin, Robert Guy, Swager, Timothy M
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2013
Online Access:http://hdl.handle.net/1721.1/82074
https://orcid.org/0000-0003-1589-832X