Monoaryloxide Pyrrolide (MAP) Imido Alkylidene Complexes of Molybdenum and Tungsten That Contain 2,6-Bis(2,5-R[subscript 2]-pyrrolyl)phenoxide (R = i-Pr, Ph) Ligands and an Unsubstituted Metallacyclobutane on Its Way to Losing Ethylene

Monoaryloxide Pyrrolide (MAP) Imido Alkylidene Complexes of Molybdenum and Tungsten That Contain 2,6-Bis(2,5-R[subscript 2]-pyrrolyl)phenoxide (R = i-Pr, Ph) Ligands and an Unsubstituted Metallacyclobutane on Its Way to Losing Ethylene

We report the synthesis of Mo and W MAP complexes that contain O-2,6-(2,5-R[subscript 2]-pyrrolyl)[subscript 2]C[subscript 6]H[subscript 3] (2,6-dipyrrolylphenoxide or ODPP[superscript R]) ligands in which R = i-Pr, Ph. W(NAr)(CH-t-Bu)(Pyr)(ODPP[superscript Ph]) (4a; Ar = 2,6-disopropylphenyl, Pyr =...

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Bibliographic Details
Main Authors: Reithofer, Michael R., Dobereiner, Graham E., Schrock, Richard Royce, Muller, Peter
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2013
Online Access:http://hdl.handle.net/1721.1/82093
https://orcid.org/0000-0001-5827-3552

Internet

http://hdl.handle.net/1721.1/82093
https://orcid.org/0000-0001-5827-3552

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