Modeling the Syn Disposition of Nitrogen Donors in Non-Heme Diiron Enzymes. Synthesis, Characterization, and Hydrogen Peroxide Reactivity of Diiron(III) Complexes with the Syn N-Donor Ligand H[subscript 2]BPG[subscript 2]DEV

Modeling the Syn Disposition of Nitrogen Donors in Non-Heme Diiron Enzymes. Synthesis, Characterization, and Hydrogen Peroxide Reactivity of Diiron(III) Complexes with the Syn N-Donor Ligand H[subscript 2]BPG[subscript 2]DEV

In order to model the syn disposition of histidine residues in carboxylate-bridged non-heme diiron enzymes, we prepared a new dinucleating ligand, H[subscript 2]BPG[subscript 2]DEV, that provides this geometric feature. The ligand incorporates biologically relevant carboxylate functionalities, which...

ver descrição completa

Detalhes bibliográficos
Principais autores: Friedle, Simone, Kodanko, Jeremy J., Morys, Anna J., Hayashi, Takahiro, Lippard, Stephen J., Moenne-Loccoz, Pierre
Outros Autores: Massachusetts Institute of Technology. Department of Chemistry
Formato: Artigo
Idioma:en_US
Publicado em: American Chemical Society (ACS) 2013
Acesso em linha:http://hdl.handle.net/1721.1/82142
https://orcid.org/0000-0002-2693-4982

Internet

http://hdl.handle.net/1721.1/82142
https://orcid.org/0000-0002-2693-4982

Registros relacionados