Concise Total Synthesis and Stereochemical Revision of (+)-Naseseazines A and B: Regioselective Arylative Dimerization of Diketopiperazine Alkaloids
Concise and enantioselective total syntheses of (+)-naseseazines A and B are described. Our regioselective and directed dimerization of diketopiperazines provides their critical C3–C[2 over sp] linkages, an assembly with plausible biogenetic relevance. We revise the absolute stereochemistry of (+)-n...
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| 格式: | 文件 |
| 语言: | en_US |
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American Chemical Society (ACS)
2013
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| 在线阅读: | http://hdl.handle.net/1721.1/82465 https://orcid.org/0000-0003-3080-1063 |