Z-Selective Olefin Metathesis Reactions Promoted by Tungsten Oxo Alkylidene Complexes

Z-Selective Olefin Metathesis Reactions Promoted by Tungsten Oxo Alkylidene Complexes

Addition of LiOHMT (OHMT = O-2,6-dimesitylphenoxide) to W(O)(CH-t-Bu)(PMe[subscript 2]Ph)[subscript 2]Cl[subscript 2] led to WO(CH-t-Bu)Cl(OHMT)(PMe[subscript 2]Ph) (4). Subsequent addition of Li(2,5-Me[subscript 2]C[subscript 4]H[subscript 2]N) to 4 yielded yellow W(O)(CH-t-Bu)(OHMT)(Me[subscript 2...

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Bibliographic Details
Main Authors: Takase, Michael K., Hoveyda, Amir H., Peryshkov, Dmitry, Schrock, Richard Royce, Muller, Peter
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2013
Online Access:http://hdl.handle.net/1721.1/82554
https://orcid.org/0000-0001-5827-3552

Internet

http://hdl.handle.net/1721.1/82554
https://orcid.org/0000-0001-5827-3552

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