Isolation of Pure Disubstituted E Olefins through Mo-Catalyzed Z-Selective Ethenolysis of Stereoisomeric Mixtures
Monoaryloxide–pyrrolide (MAP) complexes of molybdenum were employed for the selective ethenolysis of 1,2-disubstituted Z olefins in the presence of the corresponding E olefins. Reactions were performed in the presence of 0.02–3.0 mol % catalyst at 22 °C under 20 atm ethylene. We have demonstrated th...
| Główni autorzy: | , , , , |
|---|---|
| Kolejni autorzy: | |
| Format: | Artykuł |
| Język: | en_US |
| Wydane: |
American Chemical Society
2013
|
| Dostęp online: | http://hdl.handle.net/1721.1/82578 https://orcid.org/0000-0001-5827-3552 |