Comparative PCET Study of a Donor−Acceptor Pair Linked by Ionized and Nonionized Asymmetric Hydrogen-Bonded Interfaces

A Zn(II) amidinium porphyrin is the excited-state electron donor (D) to a naphthalene diimide acceptor (A) appended with either a carboxylate or sulfonate functionality. The two-point hydrogen bond (···[H[superscript +]]···) formed between the amidinium and carboxylate or sulfonate functionalities e...

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Bibliographic Details
Main Authors: Young, Elizabeth R., Rosenthal, Joel, Hodgkiss, Justin M., Nocera, Daniel G.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2013
Online Access:http://hdl.handle.net/1721.1/82587
https://orcid.org/0000-0002-4507-1115