Five-Coordinate Rearrangements of Metallacyclobutane Intermediates During Ring-Opening Metathesis Polymerization (ROMP) of 2,3-Dicarboalkoxynorbornenes by Molybdenum and Tungsten Monoalkoxide Pyrrolide (MAP) Initiators

Five-Coordinate Rearrangements of Metallacyclobutane Intermediates During Ring-Opening Metathesis Polymerization (ROMP) of 2,3-Dicarboalkoxynorbornenes by Molybdenum and Tungsten Monoalkoxide Pyrrolide (MAP) Initiators

Addition of rac-DCENBE (2,3-dicarboethoxynorbornene) or rac-DCBNBE (2,3-dicarbo-tert-butoxynorbornene) to Mo(NAd)(CHCMe[subscript 2]Ph)(Pyr)(OHMT) (1a) (Ad = 1-adamantyl, OHMT = 2,6-dimesitylphenoxide, Pyr– = NC[subscript 4]H[subscript 4]–) led to the formation of polymers that have a cis,syndiotact...

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Bibliographic Details
Main Authors: Flook, Margaret M., Kilyanek, Stefan M., Gerber, Laura C. H., Borner, Janna, Schrock, Richard Royce
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2014
Online Access:http://hdl.handle.net/1721.1/84101
https://orcid.org/0000-0001-5827-3552

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http://hdl.handle.net/1721.1/84101
https://orcid.org/0000-0001-5827-3552

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