Syntheses of Tungsten tert-Butylimido and Adamantylimido Alkylidene Complexes Employing Pyridinium Chloride as the Acid
Routes to new tungsten alkylidene complexes that contain tert-butylimido or adamantylimido ligands have been devised that begin with a reaction between WCl[subscript 6] and 4 equivalents of HNR(TMS) to give [W(NR)[subscript 2]Cl(μ-Cl)(RNH[subscript 2])][subscript 2] (R = t-Bu or 1-adamantyl). Alkyla...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society (ACS)
2014
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| Online Access: | http://hdl.handle.net/1721.1/84531 https://orcid.org/0000-0002-1788-4100 https://orcid.org/0000-0001-5827-3552 |