Synthesis of Tungsten Oxo Alkylidene Complexes

Reaction of W(O)[subscript 2](CH[subscript 2]-t-Bu)[subscript 2](bipy) with a mixture of ZnCl[subscript 2](dioxane), PMe[subscript 2]Ph, and trimethylsilyl chloride in toluene at 100 °C produced the known tungsten oxo alkylidene complex W(O)(CH-t-Bu)Cl[subscript 2](PMe[subscript 2]Ph)[subscript 2] (...

Full description

Bibliographic Details
Main Authors: Peryshkov, Dmitry, Schrock, Richard Royce
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2014
Online Access:http://hdl.handle.net/1721.1/84532
https://orcid.org/0000-0001-5827-3552