Cis, Isotactic Selective ROMP of Norbornenes Fused with N-Arylpyrrolidines. Double Stranded Polynorbornene-Based Ladderphanes with Z-Double Bonds

Upon treatment with a molybdenum-carbene with bidentate substituted biaryl-o,o′-diphenoxide ligand 12, norbornene fused with N-aryl-endo-pyrrolidine 9a undergoes ROMP to give exclusively polynorbornene with cis, isotactic-selectivity. Bis(norbornenes) connected with ferrocene 18 or benzene 20 linker...

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Bibliographic Details
Main Authors: Zhu, Lei, Flook, Margaret M., Lee, Shern-Long, Chan, Li-Wei, Huang, Shou-Ling, Chiu, Ching-Wen, Chen, Chun-Hsien, Luh, Tien-Yau, Schrock, Richard Royce
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2014
Online Access:http://hdl.handle.net/1721.1/84538
https://orcid.org/0000-0001-5827-3552