Cyclobutadiene–C[subscript 60] Adducts: N-Type Materials for Organic Photovoltaic Cells with High V[subscript OC]

New tetraalkylcyclobutadiene–C[subscript 60] adducts are developed via Diels–Alder cycloaddition of C[subscript 60] with in situ generated cyclobutadienes. The cofacial π-orbital interactions between the fullerene orbitals and the cyclobutene are shown to decrease the electron affinity and thereby i...

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Bibliographic Details
Main Authors: Han, Ggoch Ddeul, Collins, William R., Andrew, Trisha Lionel, Bulovic, Vladimir, Swager, Timothy Manning
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: Wiley Blackwell 2014
Online Access:http://hdl.handle.net/1721.1/84598
https://orcid.org/0000-0002-0960-2580