Reversible binding of nitric oxide to an Fe(iii) complex of a tetra-amido macrocycle
Nitric oxide binds reversibly to the Fe(III) complex of a well-developed tetra-amido macrocyclic ligand. Reaction with NO results in formation of a species consistent with an S = 1 {Fe–NO}[superscript 6] ground state as characterized by UV-vis, IR, EPR, and Mössbauer spectroscopy. The resultant nitr...
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Format: | Article |
Language: | en_US |
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Royal Society of Chemistry
2014
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Online Access: | http://hdl.handle.net/1721.1/84620 https://orcid.org/0000-0002-2693-4982 |