Reversible binding of nitric oxide to an Fe(iii) complex of a tetra-amido macrocycle

Nitric oxide binds reversibly to the Fe(III) complex of a well-developed tetra-amido macrocyclic ligand. Reaction with NO results in formation of a species consistent with an S = 1 {Fe–NO}[superscript 6] ground state as characterized by UV-vis, IR, EPR, and Mössbauer spectroscopy. The resultant nitr...

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Bibliographic Details
Main Authors: Pluth, Michael D., Lippard, Stephen J.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: Royal Society of Chemistry 2014
Online Access:http://hdl.handle.net/1721.1/84620
https://orcid.org/0000-0002-2693-4982