Synthesis and ROMP Chemistry of Decafluoroterphenoxide Molybdenum Imido Alkylidene and Ethylene Complexes

The bisDFTO alkylidene complexes of molybdenum Mo(NR)(CHCMe2Ph)(DFTO)2 (R = 2,6-i-Pr2C6H3, 2,6-Me2C6H3, C6F5, 1-adamantyl; DFTO = 2,6-(C6F5)2C6H3O) and monoaryloxide monopyrrolide (MAP) complexes Mo(NR)(CHCMe2Ph)(Me2Pyr)(OAr) (Me2Pyr = 2,5-dimethylpyrrolide; R = C6F5, OAr = DFTO, 2,6-dimesitylphenox...

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Bibliographic Details
Main Authors: Yuan, Jian, Schrock, Richard Royce, Gerber, Laura C. H., Muller, Peter, Smith, Stacey
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society 2014
Online Access:http://hdl.handle.net/1721.1/86910
https://orcid.org/0000-0001-5827-3552