Designed Single-Step Synthesis, Structure, and Derivative Textural Properties of Well-Ordered Layered Penta-coordinate Silicon Alcoholate Complexes

The controllable synthesis of well-ordered layered materials with specific nanoarchitecture poses a grand challenge in materials chemistry. Here the solvothermal synthesis of two structurally analogous 5-coordinate organosilicate complexes through a novel transesterification mechanism is reported. S...

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Bibliographic Details
Main Authors: Li, Xiansen, Michaelis, Vladimir K., Ong, Ta-Chung, Smith, Stacey J., Griffin, Robert Guy, Wang, Evelyn
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: John Wiley & Sons, Inc 2014
Online Access:http://hdl.handle.net/1721.1/87685
https://orcid.org/0000-0003-1589-832X
https://orcid.org/0000-0002-6708-7660
https://orcid.org/0000-0001-7045-1200