Direct observation of ground-state lactam-lactim tautomerization using temperature-jump transient 2D IR spectroscopy

We provide a systematic characterization of the nanosecond ground-state lactam-lactim tautomerization of pyridine derivatives in aqueous solution under ambient conditions using temperature-jump transient 2D IR spectroscopy. Although electronic excited-state tautomerization has been widely studied, e...

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Dades bibliogràfiques
Autors principals: Peng, Chunte Sam, Biaz, Carlos R., Tokmakoff, Andrei
Altres autors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Idioma:en_US
Publicat: National Academy of Sciences (U.S.) 2014
Accés en línia:http://hdl.handle.net/1721.1/88253