Z-Selective Ring-Opening Metathesis Polymerization of 3-Substituted Cyclooctenes by Monoaryloxide Pyrrolide Imido Alkylidene (MAP) Catalysts of Molybdenum and Tungsten

Z-Selective Ring-Opening Metathesis Polymerization of 3-Substituted Cyclooctenes by Monoaryloxide Pyrrolide Imido Alkylidene (MAP) Catalysts of Molybdenum and Tungsten

Ring-opening metathesis polymerization of a series of 3-substituted cyclooctenes (3-MeCOE, 3-HexCOE, and 3-PhCOE) initiated by various Mo and W MAP complexes leads to cis,HT-poly(3-RCOE) polymers. The apparent rate of polymerization of 3-HexCOE by W(N-t-Bu)(CH-t-Bu)(Pyr)(OHMT) (1c; Pyr = pyrrolide;...

ver descrição completa

Detalhes bibliográficos
Principais autores: Jeong, Hyangsoo, Kozera, Daniel J., Smith, Stacey J., Zhang, Jihua, Ren, Ning, Hillmyer, Marc A., Schrock, Richard Royce
Outros Autores: Massachusetts Institute of Technology. Department of Chemistry
Formato: Artigo
Idioma:en_US
Publicado em: American Chemical Society (ACS) 2014
Acesso em linha:http://hdl.handle.net/1721.1/89053
https://orcid.org/0000-0002-1788-4100
https://orcid.org/0000-0001-5827-3552

Internet

http://hdl.handle.net/1721.1/89053
https://orcid.org/0000-0002-1788-4100
https://orcid.org/0000-0001-5827-3552

Registros relacionados