Z-Selective Ring-Opening Metathesis Polymerization of 3-Substituted Cyclooctenes by Monoaryloxide Pyrrolide Imido Alkylidene (MAP) Catalysts of Molybdenum and Tungsten
Ring-opening metathesis polymerization of a series of 3-substituted cyclooctenes (3-MeCOE, 3-HexCOE, and 3-PhCOE) initiated by various Mo and W MAP complexes leads to cis,HT-poly(3-RCOE) polymers. The apparent rate of polymerization of 3-HexCOE by W(N-t-Bu)(CH-t-Bu)(Pyr)(OHMT) (1c; Pyr = pyrrolide;...
| Main Authors: | , , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society (ACS)
2014
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| Online Access: | http://hdl.handle.net/1721.1/89053 https://orcid.org/0000-0002-1788-4100 https://orcid.org/0000-0001-5827-3552 |