Uptake of one and two molecules of CO[subscript 2] by the molybdate dianion: a soluble, molecular oxide model system for carbon dioxide fixation
Tetrahedral [MoO4][superscript 2−] readily binds CO[subscript 2] at room temperature to produce a robust monocarbonate complex, [MoO[subscript 3](κ[superscript 2]-CO[subscript 3])][superscript 2−], that does not release CO[subscript 2] even at modestly elevated temperatures (up to 56 °C in solution...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
Royal Society of Chemistry
2014
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| Online Access: | http://hdl.handle.net/1721.1/90855 https://orcid.org/0000-0002-1335-9755 https://orcid.org/0000-0003-2568-3269 |