Cahn-Hilliard Reaction Model for Isotropic Li-ion Battery Particles

Using the recently developed Cahn-Hilliard reaction (CHR) theory, we present a simple mathematical model of the transition from solid-solution radial diffusion to two-phase shrinking-core dynamics during ion intercalation in a spherical solid particle. This general approach extends previous Li-ion b...

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Bibliographic Details
Main Authors: Zeng, Yi, Bazant, Martin Z.
Other Authors: Massachusetts Institute of Technology. Department of Chemical Engineering
Format: Article
Language:en_US
Published: Cambridge University Press/Materials Research Society 2014
Online Access:http://hdl.handle.net/1721.1/91228