An Improved Catalyst System for the Pd-Catalyzed Fluorination of (Hetero)Aryl Triflates

The stable Pd(0) species [(1,5-cyclooctadiene)(L·Pd)[subscript 2]] (L = AdBrettPhos) has been prepared and successfully evaluated as a precatalyst for the fluorination of aryl triflates derived from biologically active and heteroaryl phenols, challenging substrates for our previously reported cataly...

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Bibliographic Details
Main Authors: Lee, Hong Geun, Buchwald, Stephen Leffler, Milner, Phillip John
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: American Chemical Society (ACS) 2015
Online Access:http://hdl.handle.net/1721.1/94490
https://orcid.org/0000-0003-3875-4775
https://orcid.org/0000-0001-8075-1100