A General, Practical Palladium-Catalyzed Cyanation of (Hetero)Aryl Chlorides and Bromides

Playing it safe: The nontoxic cyanide source K[subscript 4][Fe(CN)[subscript 6]⋅3 H[subscript 2]O can be used for the cyanation of (hetero)aryl halides. The application of palladacycle catalysts prevents poisoning during catalyst formation, thereby allowing for low catalyst loadings, fast reaction t...

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Bibliographic Details
Main Authors: Senecal, Todd D., Shu, Wei, Buchwald, Stephen Leffler
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: Wiley Blackwell 2015
Online Access:http://hdl.handle.net/1721.1/94498
https://orcid.org/0000-0003-3875-4775