Versatile Reactivity of a Solvent-Coordinated Diiron(II) Compound: Synthesis and Dioxygen Reactivity of a Mixed-Valent Fe [superscript II] Fe [superscript III] Species
A new, DMF-coordinated, preorganized diiron compound [Fe[subscript 2](N-Et-HPTB)(DMF)[subscript 4]](BF[subscript 4])[subscript 3] (1) was synthesized, avoiding the formation of [Fe(N-Et-HPTB)](BF4)2 (10) and [Fe2(N-Et-HPTB)(μ-MeCONH)](BF[subscript 4])[subscript 2] (11), where N-Et-HPTB is the anion...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society (ACS)
2015
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| Online Access: | http://hdl.handle.net/1721.1/95498 https://orcid.org/0000-0002-2693-4982 https://orcid.org/0000-0002-1577-2420 |