Observation of the simplest Criegee intermediate CH[subscript 2]OO in the gas-phase ozonolysis of ethylene

Ozonolysis is one of the dominant oxidation pathways for tropospheric alkenes. Although numerous studies have confirmed a 1,3-cycloaddition mechanism that generates a Criegee intermediate (CI) with form R[subscript 1]R[subscript 2]COO, no small CIs have ever been directly observed in the ozonolysis...

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Main Authors: Womack, Caroline C., Martin-Drumel, Marie-Aline, Brown, Gordon G., Field, Robert W., McCarthy, Michael C.
其他作者: Massachusetts Institute of Technology. Department of Chemistry
格式: 文件
语言:en_US
出版: American Association for the Advancement of Science (AAAS) 2015
在线阅读:http://hdl.handle.net/1721.1/96419
https://orcid.org/0000-0002-7609-4205