Ligand-Controlled Asymmetric Arylation of Aliphatic α-Amino Anion Equivalents
A palladium-catalyzed asymmetric arylation of 9-aminofluorene-derived imines using a chiral dialkylbiaryl phosphine as the supporting ligand has been developed. This transformation allows for enantioselective access to a diverse range of α-branched benzylamines.
Main Authors: | Zhu, Ye, Buchwald, Stephen Leffler |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
American Chemical Society (ACS)
2015
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Online Access: | http://hdl.handle.net/1721.1/96508 https://orcid.org/0000-0002-8566-576X https://orcid.org/0000-0003-3875-4775 |
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