Mild Pd-Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst

A palladacyclic precatalyst is employed to cleanly generate a highly active XantPhos-ligated Pd-catalyst. Its use in low temperature aminocarbonylations of (hetero)aryl bromides provides access to a range of challenging products in good to excellent yields with low catalyst loading and only a slight...

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Bibliografski detalji
Glavni autori: Skrydstrup, Troels, Friis, Stig, Buchwald, Stephen Leffler
Daljnji autori: Massachusetts Institute of Technology. Department of Chemistry
Format: Članak
Jezik:en_US
Izdano: American Chemical Society (ACS) 2015
Online pristup:http://hdl.handle.net/1721.1/99675
https://orcid.org/0000-0002-2624-915X
https://orcid.org/0000-0003-3875-4775