Turning bubbles on and off during boiling using charged surfactants

Boiling—a process that has powered industries since the steam age—is governed by bubble formation. State-of-the-art boiling surfaces often increase bubble nucleation via roughness and/or wettability modification to increase performance. However, without active in situ control of bubbles, temperature...

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Main Authors: Mizerak, Jordan P., Wang, Evelyn N., Cho, Han-Jae Jeremy
Other Authors: Massachusetts Institute of Technology. Department of Mechanical Engineering
Format: Article
Language:en_US
Published: Nature Publishing Group 2015
Online Access:http://hdl.handle.net/1721.1/99742
https://orcid.org/0000-0002-8272-690X
https://orcid.org/0000-0002-8338-4841
https://orcid.org/0000-0001-7045-1200
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author Mizerak, Jordan P.
Wang, Evelyn N.
Cho, Han-Jae Jeremy
author2 Massachusetts Institute of Technology. Department of Mechanical Engineering
author_facet Massachusetts Institute of Technology. Department of Mechanical Engineering
Mizerak, Jordan P.
Wang, Evelyn N.
Cho, Han-Jae Jeremy
author_sort Mizerak, Jordan P.
collection MIT
description Boiling—a process that has powered industries since the steam age—is governed by bubble formation. State-of-the-art boiling surfaces often increase bubble nucleation via roughness and/or wettability modification to increase performance. However, without active in situ control of bubbles, temperature or steam generation cannot be adjusted for a given heat input. Here we report the ability to turn bubbles ‘on and off’ independent of heat input during boiling both temporally and spatially via molecular manipulation of the boiling surface. As a result, we can rapidly and reversibly alter heat transfer performance up to an order of magnitude. Our experiments show that this active control is achieved by electrostatically adsorbing and desorbing charged surfactants to alter the wettability of the surface, thereby affecting nucleation. This approach can improve performance and flexibility in existing boiling technologies as well as enable emerging or unprecedented energy applications.
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spelling mit-1721.1/997422022-10-01T17:49:01Z Turning bubbles on and off during boiling using charged surfactants Mizerak, Jordan P. Wang, Evelyn N. Cho, Han-Jae Jeremy Massachusetts Institute of Technology. Department of Mechanical Engineering Cho, Han-Jae Jeremy Mizerak, Jordan P. Wang, Evelyn N. Boiling—a process that has powered industries since the steam age—is governed by bubble formation. State-of-the-art boiling surfaces often increase bubble nucleation via roughness and/or wettability modification to increase performance. However, without active in situ control of bubbles, temperature or steam generation cannot be adjusted for a given heat input. Here we report the ability to turn bubbles ‘on and off’ independent of heat input during boiling both temporally and spatially via molecular manipulation of the boiling surface. As a result, we can rapidly and reversibly alter heat transfer performance up to an order of magnitude. Our experiments show that this active control is achieved by electrostatically adsorbing and desorbing charged surfactants to alter the wettability of the surface, thereby affecting nucleation. This approach can improve performance and flexibility in existing boiling technologies as well as enable emerging or unprecedented energy applications. Singapore-MIT Alliance for Research and Technology National Science Foundation (U.S.). Materials Research Science and Engineering Centers (Program) (Award DMR-0819762) 2015-11-09T12:56:22Z 2015-11-09T12:56:22Z 2015-10 2015-05 Article http://purl.org/eprint/type/JournalArticle 2041-1723 http://hdl.handle.net/1721.1/99742 Cho, H. Jeremy, Jordan P. Mizerak, and Evelyn N. Wang. “Turning Bubbles on and Off During Boiling Using Charged Surfactants.” Nat Comms 6 (October 21, 2015): 8599. © 2015 Macmillan Publishers Limited https://orcid.org/0000-0002-8272-690X https://orcid.org/0000-0002-8338-4841 https://orcid.org/0000-0001-7045-1200 en_US http://dx.doi.org/10.1038/ncomms9599 Nature Communications Creative Commons Attribution http://creativecommons.org/licenses/by/4.0/ application/pdf Nature Publishing Group Nature
spellingShingle Mizerak, Jordan P.
Wang, Evelyn N.
Cho, Han-Jae Jeremy
Turning bubbles on and off during boiling using charged surfactants
title Turning bubbles on and off during boiling using charged surfactants
title_full Turning bubbles on and off during boiling using charged surfactants
title_fullStr Turning bubbles on and off during boiling using charged surfactants
title_full_unstemmed Turning bubbles on and off during boiling using charged surfactants
title_short Turning bubbles on and off during boiling using charged surfactants
title_sort turning bubbles on and off during boiling using charged surfactants
url http://hdl.handle.net/1721.1/99742
https://orcid.org/0000-0002-8272-690X
https://orcid.org/0000-0002-8338-4841
https://orcid.org/0000-0001-7045-1200
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