Reactivity of cycloplatinated amine complexes : intramolecular C–C bond formation, C–H activation, and PPh2 migration in coordinated alkynylphosphines
The monomeric ortho-platinated complexes [Pt{R1CH(1-C6H4)NMe2-C,N}{Ph2PC≡CR2}Cl] (R1 = Me, Et; R2 = Me, Ph) with trans-N,P geometries were obtained regiospecifically from the reaction between the dimeric [Pt2(μ-Cl)2{R1CH(1-C6H4)NMe2-C,N}2] and the corresponding alkynylphosphines in high yields. The...
| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/101108 http://hdl.handle.net/10220/13696 |