The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes
The reaction of [Cp*RhCl2]2 with an aniline (R′NH2) and a terminal alkyne (RCCH) afforded the N-containing cyclometalated rhodium complexes Cp*Rh(Cl)[N(R′)=C(CH2R)-CH=CR] via a hydroamination and a 1,2-insertion of an alkyne. A reaction pathway has been proposed on the basis of deuterium labeling ex...
| Main Authors: | , |
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| 格式: | Journal Article |
| 语言: | English |
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2014
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| 在线阅读: | https://hdl.handle.net/10356/101380 http://hdl.handle.net/10220/18615 |