Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework
Coordination of a tetratopic nitrogen-rich linker with Zn2+ under solvothermal conditions afforded a Zn-based metal organic framework (MOF), where the Zn(II) ions could be exchanged by Cu(II) ions in a single-crystal-to-single-crystal fashion leading to a new Cu-based MOF. Such transformation induce...
Main Authors: | , , , , , , , , , |
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Other Authors: | |
Format: | Journal Article |
Language: | English |
Published: |
2013
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Online Access: | https://hdl.handle.net/10356/101388 http://hdl.handle.net/10220/11111 |