Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework
Coordination of a tetratopic nitrogen-rich linker with Zn2+ under solvothermal conditions afforded a Zn-based metal organic framework (MOF), where the Zn(II) ions could be exchanged by Cu(II) ions in a single-crystal-to-single-crystal fashion leading to a new Cu-based MOF. Such transformation induce...
| Main Authors: | , , , , , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/101388 http://hdl.handle.net/10220/11111 |
| _version_ | 1824453602871083008 |
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| author | Rakesh, Ganguly Wang, Xiao-Jun Li, Pei-Zhou Liu, Lei Zhang, Quan Borah, Parijat Wong, Jinye Daniel Chan, Xiu Xiang Li, Yongxin Zhao, Yanli |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Rakesh, Ganguly Wang, Xiao-Jun Li, Pei-Zhou Liu, Lei Zhang, Quan Borah, Parijat Wong, Jinye Daniel Chan, Xiu Xiang Li, Yongxin Zhao, Yanli |
| author_sort | Rakesh, Ganguly |
| collection | NTU |
| description | Coordination of a tetratopic nitrogen-rich linker with Zn2+ under solvothermal conditions afforded a Zn-based metal organic framework (MOF), where the Zn(II) ions could be exchanged by Cu(II) ions in a single-crystal-to-single-crystal fashion leading to a new Cu-based MOF. Such transformation induces a significant enhancement in gas sorption along with a high selectivity towards CO2 over N2 and CH4. |
| first_indexed | 2025-02-19T03:09:02Z |
| format | Journal Article |
| id | ntu-10356/101388 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2025-02-19T03:09:02Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/1013882020-06-01T10:21:29Z Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework Rakesh, Ganguly Wang, Xiao-Jun Li, Pei-Zhou Liu, Lei Zhang, Quan Borah, Parijat Wong, Jinye Daniel Chan, Xiu Xiang Li, Yongxin Zhao, Yanli School of Materials Science & Engineering School of Physical and Mathematical Sciences Coordination of a tetratopic nitrogen-rich linker with Zn2+ under solvothermal conditions afforded a Zn-based metal organic framework (MOF), where the Zn(II) ions could be exchanged by Cu(II) ions in a single-crystal-to-single-crystal fashion leading to a new Cu-based MOF. Such transformation induces a significant enhancement in gas sorption along with a high selectivity towards CO2 over N2 and CH4. 2013-07-10T06:45:38Z 2019-12-06T20:37:44Z 2013-07-10T06:45:38Z 2019-12-06T20:37:44Z 2012 2012 Journal Article Wang, X.-J., Li, P.-Z., Liu, L., Zhang, Q., Borah, P., Wong, J. D., et al. (2012). Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework. Chemical Communications, 48(83), 10268-10288. https://hdl.handle.net/10356/101388 http://hdl.handle.net/10220/11111 10.1039/c2cc34921c en Chemical communications © 2012 The Royal Society of Chemistry. |
| spellingShingle | Rakesh, Ganguly Wang, Xiao-Jun Li, Pei-Zhou Liu, Lei Zhang, Quan Borah, Parijat Wong, Jinye Daniel Chan, Xiu Xiang Li, Yongxin Zhao, Yanli Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework |
| title | Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework |
| title_full | Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework |
| title_fullStr | Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework |
| title_full_unstemmed | Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework |
| title_short | Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework |
| title_sort | significant gas uptake enhancement by post exchange of zinc ii with copper ii within a metal organic framework |
| url | https://hdl.handle.net/10356/101388 http://hdl.handle.net/10220/11111 |
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