A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion

A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion

The aromatic low-valent lead analogue of an indenyl anion (see scheme; 1) undergoes oxidation with SnCl2 to form the base-stabilized lead(I) dimer 2. Reduction of 2 with lithium regenerates 1. These compounds were characterized by NMR spectroscopy and X-ray crystallography.

Bibliographic Details
Main Authors: Chia, Siew-Peng, Xi, Hong Wei, Li, Yongxin, Lim, Kok Hwa, So, Cheuk-Wai
Other Authors: School of Chemical and Biomedical Engineering
Format: Journal Article
Language:English
Published: 2013
Subjects:
DRNTU::Science::Biological sciences::Biochemistry
DRNTU::Science::Biological sciences::Biophysics
Online Access:https://hdl.handle.net/10356/101466
http://hdl.handle.net/10220/16493

Internet

https://hdl.handle.net/10356/101466
http://hdl.handle.net/10220/16493

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