A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion
The aromatic low-valent lead analogue of an indenyl anion (see scheme; 1) undergoes oxidation with SnCl2 to form the base-stabilized lead(I) dimer 2. Reduction of 2 with lithium regenerates 1. These compounds were characterized by NMR spectroscopy and X-ray crystallography.
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/101466 http://hdl.handle.net/10220/16493 |
| _version_ | 1826126193184735232 |
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| author | Chia, Siew-Peng Xi, Hong Wei Li, Yongxin Lim, Kok Hwa So, Cheuk-Wai |
| author2 | School of Chemical and Biomedical Engineering |
| author_facet | School of Chemical and Biomedical Engineering Chia, Siew-Peng Xi, Hong Wei Li, Yongxin Lim, Kok Hwa So, Cheuk-Wai |
| author_sort | Chia, Siew-Peng |
| collection | NTU |
| description | The aromatic low-valent lead analogue of an indenyl anion (see scheme; 1) undergoes oxidation with SnCl2 to form the base-stabilized lead(I) dimer 2. Reduction of 2 with lithium regenerates 1. These compounds were characterized by NMR spectroscopy and X-ray crystallography. |
| first_indexed | 2024-10-01T06:48:41Z |
| format | Journal Article |
| id | ntu-10356/101466 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:48:41Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/1014662020-03-07T12:34:50Z A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion Chia, Siew-Peng Xi, Hong Wei Li, Yongxin Lim, Kok Hwa So, Cheuk-Wai School of Chemical and Biomedical Engineering School of Physical and Mathematical Sciences DRNTU::Science::Biological sciences::Biochemistry DRNTU::Science::Biological sciences::Biophysics The aromatic low-valent lead analogue of an indenyl anion (see scheme; 1) undergoes oxidation with SnCl2 to form the base-stabilized lead(I) dimer 2. Reduction of 2 with lithium regenerates 1. These compounds were characterized by NMR spectroscopy and X-ray crystallography. 2013-10-14T08:44:26Z 2019-12-06T20:39:00Z 2013-10-14T08:44:26Z 2019-12-06T20:39:00Z 2013 2013 Journal Article Chia, S. P., Xi, H. W., Li, Y., Lim, K. H., & So, C. W. (2013). A Base-Stabilized Lead(I) Dimer and an Aromatic Plumbylidenide Anion. Angewandte Chemie International Edition, 52(24), 6298-6301. 1433-7851 https://hdl.handle.net/10356/101466 http://hdl.handle.net/10220/16493 10.1002/anie.201301954 en Angewandte chemie international edition |
| spellingShingle | DRNTU::Science::Biological sciences::Biochemistry DRNTU::Science::Biological sciences::Biophysics Chia, Siew-Peng Xi, Hong Wei Li, Yongxin Lim, Kok Hwa So, Cheuk-Wai A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion |
| title | A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion |
| title_full | A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion |
| title_fullStr | A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion |
| title_full_unstemmed | A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion |
| title_short | A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion |
| title_sort | base stabilized lead i dimer and an aromatic plumbylidenide anion |
| topic | DRNTU::Science::Biological sciences::Biochemistry DRNTU::Science::Biological sciences::Biophysics |
| url | https://hdl.handle.net/10356/101466 http://hdl.handle.net/10220/16493 |
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