A concerted transfer hydrogenolysis : 1,3,2-diazaphospholene-catalyzed hydrogenation of N=N bond with ammonia-borane
1,3,2-diazaphospholenes catalyze metal-free transfer hydrogenation of a N=N double bond using ammonia–borane under mild reaction conditions, thus allowing access to various hydrazine derivatives. Kinetic and computational studies revealed that the rate-determining step involves simultaneous breakage...
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2014
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/102918 http://hdl.handle.net/10220/19141 |