A concerted transfer hydrogenolysis : 1,3,2-diazaphospholene-catalyzed hydrogenation of N=N bond with ammonia-borane
1,3,2-diazaphospholenes catalyze metal-free transfer hydrogenation of a N=N double bond using ammonia–borane under mild reaction conditions, thus allowing access to various hydrazine derivatives. Kinetic and computational studies revealed that the rate-determining step involves simultaneous breakage...
| Autori principali: | , , |
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| Altri autori: | |
| Natura: | Journal Article |
| Lingua: | English |
| Pubblicazione: |
2014
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| Soggetti: | |
| Accesso online: | https://hdl.handle.net/10356/102918 http://hdl.handle.net/10220/19141 |