N-metallacycles from [Cp*MX2]2 and alkynylpyridines : synthesis, reaction pathway, and romaticity
The reaction of [Cp*MX2]2 (M = Rh or Ir, X = Cl, Br, or I) with alkynylpyridines afforded halogen-substituted N-metallacyclic complexes. The reaction pathway has been examined through deuterium labeling and other experiments and computational studies and is proposed to proceed via halide dissociatio...
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2014
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/103001 http://hdl.handle.net/10220/24374 |