N-metallacycles from [Cp*MX2]2 and alkynylpyridines : synthesis, reaction pathway, and romaticity
The reaction of [Cp*MX2]2 (M = Rh or Ir, X = Cl, Br, or I) with alkynylpyridines afforded halogen-substituted N-metallacyclic complexes. The reaction pathway has been examined through deuterium labeling and other experiments and computational studies and is proposed to proceed via halide dissociatio...
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
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2014
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| Online Access: | https://hdl.handle.net/10356/103001 http://hdl.handle.net/10220/24374 |
| _version_ | 1811677357131431936 |
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| author | Teo, Jing Wei Sridevi, Venugopal Shanmugham Leong, Weng Kee |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Teo, Jing Wei Sridevi, Venugopal Shanmugham Leong, Weng Kee |
| author_sort | Teo, Jing Wei |
| collection | NTU |
| description | The reaction of [Cp*MX2]2 (M = Rh or Ir, X = Cl, Br, or I) with alkynylpyridines afforded halogen-substituted N-metallacyclic complexes. The reaction pathway has been examined through deuterium labeling and other experiments and computational studies and is proposed to proceed via halide dissociation followed by attack at the alkyne. These N-metallacycles exhibit aromaticity and undergo Sonogashira coupling reactions. |
| first_indexed | 2024-10-01T02:36:05Z |
| format | Journal Article |
| id | ntu-10356/103001 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T02:36:05Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | ntu-10356/1030012023-02-28T19:39:07Z N-metallacycles from [Cp*MX2]2 and alkynylpyridines : synthesis, reaction pathway, and romaticity Teo, Jing Wei Sridevi, Venugopal Shanmugham Leong, Weng Kee School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds The reaction of [Cp*MX2]2 (M = Rh or Ir, X = Cl, Br, or I) with alkynylpyridines afforded halogen-substituted N-metallacyclic complexes. The reaction pathway has been examined through deuterium labeling and other experiments and computational studies and is proposed to proceed via halide dissociation followed by attack at the alkyne. These N-metallacycles exhibit aromaticity and undergo Sonogashira coupling reactions. MOE (Min. of Education, S’pore) Accepted version 2014-12-09T04:59:02Z 2019-12-06T21:03:41Z 2014-12-09T04:59:02Z 2019-12-06T21:03:41Z 2014 2014 Journal Article Teo, J. W., Sridevi, V. S., & Leong, W. K. (2014). N-metallacycles from [Cp*MX2]2 and alkynylpyridines : synthesis, reaction pathway, and romaticity. Organometallics, 33(5), 1174-1180. https://hdl.handle.net/10356/103001 http://hdl.handle.net/10220/24374 10.1021/om401154c en Organometallics © 2014 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [Article DOI: http://dx.doi.org/10.1021/om401154c]. 12 p. application/pdf |
| spellingShingle | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds Teo, Jing Wei Sridevi, Venugopal Shanmugham Leong, Weng Kee N-metallacycles from [Cp*MX2]2 and alkynylpyridines : synthesis, reaction pathway, and romaticity |
| title | N-metallacycles from [Cp*MX2]2 and alkynylpyridines : synthesis, reaction pathway, and romaticity |
| title_full | N-metallacycles from [Cp*MX2]2 and alkynylpyridines : synthesis, reaction pathway, and romaticity |
| title_fullStr | N-metallacycles from [Cp*MX2]2 and alkynylpyridines : synthesis, reaction pathway, and romaticity |
| title_full_unstemmed | N-metallacycles from [Cp*MX2]2 and alkynylpyridines : synthesis, reaction pathway, and romaticity |
| title_short | N-metallacycles from [Cp*MX2]2 and alkynylpyridines : synthesis, reaction pathway, and romaticity |
| title_sort | n metallacycles from cp mx2 2 and alkynylpyridines synthesis reaction pathway and romaticity |
| topic | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds |
| url | https://hdl.handle.net/10356/103001 http://hdl.handle.net/10220/24374 |
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