Unraveling organocuprate complexity : fundamental insights into intrinsic group transfer selectivity in alkylation reactions

Unraveling organocuprate complexity : fundamental insights into intrinsic group transfer selectivity in alkylation reactions

The near thermal conditions of an ion-trap mass spectrometer were used to examine the intrinsic gas-phase reactivity and selectivity of nucleophilic substitution reactions. The well-defined organocuprate anions [CH3CuR]– (R = CH3CH2, CH3CH2CH2, (CH3)2CH, PhCH2CH2, PhCH2, Ph, C3H5, and H) were reacte...

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Bibliographic Details
Main Authors: Rijs, Nicole J., Yoshikai, Naohiko, Nakamura, Eiichi, O’Hair, Richard A. J.
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2014
Subjects:
DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Online Access:https://hdl.handle.net/10356/103105
http://hdl.handle.net/10220/24362

Internet

https://hdl.handle.net/10356/103105
http://hdl.handle.net/10220/24362

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