Asymmetric construction of a ferrocenyl phosphapalladacycle from achiral enones and a demonstration of its catalytic potential

A new approach toward ferrocenyl phosphapalladacycle construction from achiral enones via asymmetric hydrophosphination and subsequent diastereoselective C–H activation is described. Its catalytic efficacy toward C–C bond formation is subsequently illustrated.

Bibliographic Details
Main Authors: Gan, Kennard, Sadeer, Abdul, Xu, Chang, Li, Yongxin, Pullarkat, Sumod A.
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2014
Subjects:
Online Access:https://hdl.handle.net/10356/103794
http://hdl.handle.net/10220/24560