Catalytic activation of carbohydrates as formaldehyde equivalents for Stetter reaction with enones
We disclose the first catalytic activation of carbohydrates as formaldehyde equivalents to generate acyl anions as one-carbon nucleophilic units for a Stetter reaction. The activation involves N-heterocyclic carbene (NHC)-catalyzed C–C bond cleavage of carbohydrates via a retro-benzoin-type process...
| मुख्य लेखकों: | , , , |
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| अन्य लेखक: | |
| स्वरूप: | Journal Article |
| भाषा: | English |
| प्रकाशित: |
2014
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| विषय: | |
| ऑनलाइन पहुंच: | https://hdl.handle.net/10356/104155 http://hdl.handle.net/10220/19437 |