A silyliumylidene cation stabilized by an amidinate ligand and 4-dimethylaminopyridine

The synthesis and reactivity of a silyliumylidene cation stabilized by an amidinate ligand and 4-dimethylaminopyridine (DMAP) are described. The reaction of the amidinate silicon(I) dimer [LSi:]2 (1; L=PhC(NtBu)2) with one equivalent of N-trimethylsilyl-4-dimethylaminopyridinium triflate [4-NMe2C5H4...

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Bibliographic Details
Main Authors: Yeong, Hui-Xian, Xi, Hong Wei, Li, Yongxin, Lim, Kok Hwa, So, Cheuk-Wai
Other Authors: School of Chemical and Biomedical Engineering
Format: Journal Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/107150
http://hdl.handle.net/10220/17706
http://dx.doi.org/10.1002/chem.201300255