(Guanidine) copper complex-catalyzed enantioselective dynamic kinetic allylic alkynylation under biphasic condition

(Guanidine) copper complex-catalyzed enantioselective dynamic kinetic allylic alkynylation under biphasic condition

Highly enantioselective allylic alkynylation of racemic bromides under biphasic condition is furnished in this report. This approach employs functionalized terminal alkynes as pro-nucleophiles and provides 6- and 7-membered cyclic 1,4-enynes with high yields and excellent enantioselectivities (up to...

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Bibliografiske detaljer
Main Authors:	Cui, Xi-Yang, Ge, Yicen, Tan, Siu Min, Jiang, Huan, Tan, Davin, Lu, Yunpeng, Lee, Richmond, Tan, Choon-Hong
Andre forfattere:	School of Physical and Mathematical Sciences
Format:	Journal Article
Sprog:	English
Udgivet:	2020
Fag:	Science::Chemistry Guanidine Anions
Online adgang:	https://hdl.handle.net/10356/137033

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