Carbene-catalyzed indole 3-Methyl C(sp3)-H bond functionalization

The metal-free catalytic functionalization of aromatic sp2-carbons and benzylic sp3-carbons remains challenging. Here we report a carbene-catalyzed functionalization of the 3-methyl sp3-carbon attached to 2-formyl-indoles. The reaction proceeds through an NHC-bound o-quinodimethane as the key interm...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид: Cheng, Jian, Sun, Jun, Yan, Jiekuan, Yang, Song, Zheng, Pengcheng, Jin, Zhichao, Chi, Robin Yonggui
Бусад зохиолчид: School of Physical and Mathematical Sciences
Формат: Journal Article
Хэл сонгох:English
Хэвлэсэн: 2020
Нөхцлүүд:
Онлайн хандалт:https://hdl.handle.net/10356/137628