Carbene-catalyzed indole 3-Methyl C(sp3)-H bond functionalization
The metal-free catalytic functionalization of aromatic sp2-carbons and benzylic sp3-carbons remains challenging. Here we report a carbene-catalyzed functionalization of the 3-methyl sp3-carbon attached to 2-formyl-indoles. The reaction proceeds through an NHC-bound o-quinodimethane as the key interm...
Үндсэн зохиолчид: | , , , , , , |
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Бусад зохиолчид: | |
Формат: | Journal Article |
Хэл сонгох: | English |
Хэвлэсэн: |
2020
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Нөхцлүүд: | |
Онлайн хандалт: | https://hdl.handle.net/10356/137628 |