Addition of a carbene catalyst to indole aryl aldehyde activates a remote δ-sp2 carbon for protonation and formal [4+2] reaction

The addition of a carbene catalyst to an indole aryl aldehyde leads to the activation of a remote sp2 carbon that is five atoms away from the catalyst. The unsaturated Breslow intermediate formed between the catalyst and substrate undergoes an internal redox reaction and remote carbon protonation to...

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Main Authors: Zheng, Pengcheng, Wu, Shuquan, Mou, Chengli, Xue, Wei, Jin, Zhichao, Chi, Robin Yonggui
其他作者: School of Physical and Mathematical Sciences
格式: Journal Article
语言:English
出版: 2020
主题:
在线阅读:https://hdl.handle.net/10356/137753