Diverse bonding activations in the reactivity of a pentaphenylborole toward sodium phosphaethynolate : heterocycle synthesis and mechanistic studies

The reaction of the pentaphenylborole [(PhC)4BPh] (1) with sodium phosphaethynolate·1,4-dioxane (NaOCP(1,4-dioxane)1.7) afforded the novel sodium salt of phosphaboraheterocycle 2. It comprises anionic fused tetracyclic P/B-heterocycles that arise from multiple bond activation between the borole back...

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Detalhes bibliográficos
Principais autores: Li, Yan, Siwatch, Rahul Kumar, Mondal, Totan, Li, Yongxin, Ganguly, Rakesh, Koley, Debasis, So, Cheuk-Wai
Outros Autores: School of Physical and Mathematical Sciences
Formato: Journal Article
Idioma:English
Publicado em: 2020
Assuntos:
Acesso em linha:https://hdl.handle.net/10356/139442