Synthesis of unique phosphazane macrocycles via steric activation of C-N bonds

Synthesis of unique phosphazane macrocycles via steric activation of C-N bonds

Herein we describe that oxidation reactions of the dimeric cyclophosphazanes, [{P(μ-NR)}2(μ-NR)]2, R = tBu (1), to produce a series of diagonally dioxidized products P4(μ-N tBu)6E2 [E = O (2), S (3), and Se (4)] and tetraoxidized frameworks. The latter display an unexpected C-N bond activation and c...

Full description

Bibliographic Details
Main Authors: Shi, Xiaoyan, Martin, Katherine Ann, Liang, Rong Zheng, Star, Daniel G., Li, Yongxin, Ganguly, Rakesh, Sim, Ying, Tan, Davin, Díaz, Jesús, García, Felipe
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2020
Subjects:
Science::Chemistry
Group 16 Compounds
Bond Cleavage
Online Access:https://hdl.handle.net/10356/140059

Internet

https://hdl.handle.net/10356/140059

Similar Items