Divergent C-H oxidative radical functionalization of olefins to install tertiary alkyl motifs enabled by copper catalysis

An efficient tertiary alkylation reaction of olefins with 1,3-dicarbonyl compounds was developed by virtue of copper catalyst without the use of expensive ligands or additives. In contrast to alkyl Heck-type reaction, alkyl halide is not required. Notably, by varying the nitrogen and air atmosphere,...

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Bibliographic Details
Main Authors: Tian, Ming-Qing, Wang, Cong, Hu, Xu-Hong, Loh, Teck-Peng
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2021
Subjects:
Online Access:https://hdl.handle.net/10356/147446